The reaction, described in the April 19th issue of Nature Materials, opens the door to the creation of novel functional catalysts and applications in clean energy production.
In recent years, the knowledge that materials exhibit novel properties at the nano-scale has driven a search for functional nano-materials with useful applications. Among these, ultrathin metal oxide films have attracted attention for their application in reaction catalysis, yet mechanisms underlying this catalytic role have remained unclear.
Using a scanning tunneling microscope (STM) at ultra-low temperatures, the research team explored the dynamics of single water molecules interacting with a film of magnesium oxide (MgO) several atoms in thickness (Figure 1). They discovered that by injecting tunnelling electrons into water molecules on the MgO surface (Figure 2), they could select between dissociation pathways: excitation of the molecule’s vibrational states induced dissociation into hydroxyl (H + OH) (Figure 3 (a) and (b)), whereas excitation of its electronic states induced dissociation into atomic oxygen (O) (Figure 3 (c) and (d)) - see attached file.
The controlled dissociation of water molecules via selected reaction pathways presents unique opportunities in targeted catalysis, particularly in the production of hydrogen, a potential source of clean energy. While advancing our understanding of the dynamics of water molecules, the discovery also sets the stage for applications in the catalysis of more complex systems on insulating films.
For more information, please contact:Dr. Yousoo Kim
How brains surrender to sleep
23.06.2017 | IMP - Forschungsinstitut für Molekulare Pathologie GmbH
A new technique isolates neuronal activity during memory consolidation
22.06.2017 | Spanish National Research Council (CSIC)
An international team of scientists has proposed a new multi-disciplinary approach in which an array of new technologies will allow us to map biodiversity and the risks that wildlife is facing at the scale of whole landscapes. The findings are published in Nature Ecology and Evolution. This international research is led by the Kunming Institute of Zoology from China, University of East Anglia, University of Leicester and the Leibniz Institute for Zoo and Wildlife Research.
Using a combination of satellite and ground data, the team proposes that it is now possible to map biodiversity with an accuracy that has not been previously...
Hitzewellen in der Arktis, längere Vegetationsperioden in Europa, schwere Überschwemmungen in Westafrika – mit Hilfe des deutsch-französischen Satelliten MERLIN wollen Wissenschaftler ab 2021 die Emissionen des Treibhausgases Methan auf der Erde erforschen. Möglich macht das ein neues robustes Lasersystem des Fraunhofer-Instituts für Lasertechnologie ILT in Aachen, das eine bisher unerreichte Messgenauigkeit erzielt.
Methan entsteht unter anderem bei Fäulnisprozessen. Es ist 25-mal wirksamer als das klimaschädliche Kohlendioxid, kommt in der Erdatmosphäre aber lange nicht...
Heatwaves in the Arctic, longer periods of vegetation in Europe, severe floods in West Africa – starting in 2021, scientists want to explore the emissions of the greenhouse gas methane with the German-French satellite MERLIN. This is made possible by a new robust laser system of the Fraunhofer Institute for Laser Technology ILT in Aachen, which achieves unprecedented measurement accuracy.
Methane is primarily the result of the decomposition of organic matter. The gas has a 25 times greater warming potential than carbon dioxide, but is not as...
Hydrogen is regarded as the energy source of the future: It is produced with solar power and can be used to generate heat and electricity in fuel cells. Empa researchers have now succeeded in decoding the movement of hydrogen ions in crystals – a key step towards more efficient energy conversion in the hydrogen industry of tomorrow.
As charge carriers, electrons and ions play the leading role in electrochemical energy storage devices and converters such as batteries and fuel cells. Proton...
Die Europäische Weltraumagentur ESA gab heute grünes Licht für die industrielle Produktion von PLATO, der grössten europäischen wissenschaftlichen Mission zu Exoplaneten. Partner dieser Mission sind die Universitäten Bern und Genf.
Die Europäische Weltraumagentur ESA lanciert heute PLATO (PLAnetary Transits and Oscillation of stars), die grösste europäische wissenschaftliche Mission zur...
23.06.2017 | Veranstaltungen
22.06.2017 | Veranstaltungen
22.06.2017 | Veranstaltungen
23.06.2017 | Physik Astronomie
23.06.2017 | Ökologie Umwelt- Naturschutz
23.06.2017 | Materialwissenschaften